Hi @Tim Law
Please check the below detailed information on how "vector" extension works in Azure :-
https://gist.github.com/sageTimNewton/f20583ff1f0cf0af648bc0a0a91c0083
May I please know What version of Azure PostgreSQL flexible server are you using?
In summary, based on the above documentation, you may need to upgrade the instance to version 15 (preview) of PostgreSQL and enable the "Vector" extension under the azure.extensions server parameter.
Microsoft reference document - https://learn.microsoft.com/en-us/azure/postgresql/flexible-server/how-to-use-pgvector
Please verify if these instructions are applicable to your specific scenario.
Thank you.