HI @Arkady Karasin ,
Yes it should be possible, although the File Screen does not have all known extensions but you can select and block all file groups, and then create an exception for .doc files.
Create a File Screen Exception
https://learn.microsoft.com/en-us/windows-server/storage/fsrm/create-file-screen-exception
----------
(If the reply was helpful please don't forget to upvote or accept as answer, thank you)
Best regards,
Leon