Hi, @Piljer, Herbert
Thank you for posting in Microsoft Q&A forum.
BITS uses the IP Helper function, GetBestInterfaceEx, to determine the interface that has the best route to the specified IP address. BITS will then monitor bandwidth usage on that interface. Therefore, if the computer contains multiple network interfaces, BITS will use the interface that has the best route to the destination IP address. It is not based on the index or metric of the network interface. It is not possible to change the order of the NICs used by BITS.
For your reference:
https://learn.microsoft.com/en-us/windows/win32/bits/network-bandwidth
If the answer is the right solution, please click "Accept Answer" and kindly upvote it. If you have extra questions about this answer, please click "Add comment".