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Account which starts with MSOL_ is the account that gets created and used to pull any changes from on-premises. The account is created with a long, complex password that doesn't expire. If you have a password policy in your domain, make sure that long and complex passwords are allowed for this account.
And account that starts with AAD_ is the service account that gets created under which AD connect service runs. The AAD_ service account is created with a long, complex password that doesn't expire. A user account prefixed with AAD_ is created during installation only when Azure AD Connect is installed on Windows Server 2008 and when it's installed on a domain controller.
We would suggest not to change the user name to AAD for MSOL account.
Regarding the accounts in AD connect you can also refer below article,
Let me know if you have any further questions.
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