Hi @Ajay Kumar
Thank you for posting your query on Microsoft Q&A.
If your users devices are Win 10 or Win 11 and Azure AD joined, they will not benefit from enabling Seamless SSO. SSO should already be happening with a PRT.
If SSO is not happening for some reason on these devices via a PRT then it would be beneficial to troubleshoot that rather than enabling Seamless SSO.
You can confirm a user/device has a PRT by running the following command in a CMD prompt "dsregcmd /status". We have some details on this here - https://learn.microsoft.com/en-us/azure/active-directory/devices/troubleshoot-device-dsregcmd#sso-state
Do let me know if you have any further questions, I would be happy to help!
Please "Accept the answer" if the information helped you. This will help us and others in the community as well.