Hi
As Dwayne says, this is not an error, just that there are more RGB values that don't have a given name than those that do. If you want, you could offer the User a List of Colours which do have a name and prevent them from using a random RGB unnamed colour.
If that is an option you want to pursue then here is some sample code to show one way to do it.
This is a test example and you should try it out first. All it needs is a new Project with a Default Foem1 and a ComboBox1 and Labels 1 & 2 added via the Designer, then copy/replace the default code with this code.
' Form1 with a ComboBox1 and a Label1
' and a Label2
Option Strict On
Option Explicit On
Public Class Form1
Private Sub Form1_Load(sender As Object, e As EventArgs) Handles MyBase.Load
' from your post
Dim c As Color = Color.Red
Dim s As String = c.Name ' gives RED
c = Color.FromArgb(255, 222, 111, 200)
s = c.Name 'gives "ffde6fc8" which is
' the RGB values in Hex (as you said)
' Possible alternative
' set up a ComboBox to allow User to
' select only a KnowBolor
ComboBox1.DataSource = [Enum].GetValues(GetType(KnownColor))
End Sub
Private Sub ComboBox4_SelectedIndexChanged(sender As Object, e As EventArgs) Handles ComboBox1.SelectedIndexChanged
Dim cb As ComboBox = DirectCast(sender, ComboBox)
Dim c As Color = Color.FromKnownColor(DirectCast(cb.SelectedItem, KnownColor))
Label1.BackColor = c
Label2.Text = CInt(c.A).ToString & ", " & CInt(c.R).ToString & ", " & CInt(c.G).ToString & ", " & CInt(c.B).ToString
End Sub
End Class