Hi, you can set by logging on the mailbox or with Powershell:
https://learn.microsoft.com/en-us/exchange/recipients/room-mailboxes?view=exchserver-2019
Example:
Set-MailboxCalendarConfiguration -Identity Tony -WorkingHoursStartTime 08:00:00 -WorkingHoursEndTime 17:00:00
I would also confirm and set the Time Zone :