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Hi @Lukas Helmers ,
Welcome to post in our Q&A forum.
Based on your description, it is possible that the user account is not synced properly between your on-premises Active Directory and Azure Active Directory. I suggest checking if the user account is synced correctly and if there are any errors in the synchronization process.
You may also want to try removing the alias from your on-premises Active Directory by following these steps:
- Open Azure Active Directory and select the user account you would like to edit.
- Select Properties > Attribute Editor > Proxyaddresses and add the required alias.
- Wait for it to sync to Azure Active directory.
If there are any updates, feel free to let us know.
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