That's the wrong way to enable MFA. You can follow along here to manage MFA on the account.
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Hi,
I bought minecraft education a few months ago and after I set up my account I could access my account using email and password and did not need authenticator app. Recently I changed the password for my account and after that when I want to sign in to my account it requests to authenticate from me on the app. At the same time I want to add this account on the app so I can verify, but it asks me to verify the code in the same app which I can not. My account is school/work account. I only have verification code other than approve a request choice which also faces same problem. How I can authenticate my account and access it?
That's the wrong way to enable MFA. You can follow along here to manage MFA on the account.
--please don't forget to close up the thread here by marking answer if the reply is helpful--
Sounds like you'll need the work / school admins to reset the account so a new QR code can be generated with which you can scan in and relink the authentication device to your account.
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Try signing on here via desktop to manage authentication devices.
https://mysignins.microsoft.com/security-info
otherwise you'll need to reach out to 365 global customer service here.
Please don't forget to close up the thread here by marking answer if the reply is helpful--