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If a user already has at least one MFA method configured then they will always be prompted for MFA when accessing the "Security Info" portal. This is to prevent any bad actor from adding / removing MFA methods for the user with just their password. This would subsequently allow them to access other resources that are configured to require MFA.
The Conditional Access policies for "Securing Information Registration" become more useful for first time registration of MFA methods, i.e only allowing MFA to be registered from a hybrid or compliant device, or only inside the corp network.
I hope this helps, but if you have any further queries just let me know.
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