
Hi @Sayantan Ganguly,
Per my test, I could get site owners by following powershell script
#Variables for Admin Center & Site Collection URL
$AdminCenterURL = "https://tenant-admin.sharepoint.com"
#Connect to SharePoint Online
Connect-SPOService -url $AdminCenterURL -Credential (Get-Credential)
#sharepoint online powershell get site owner
Get-SPOSite -limit ALL | Select URL, Owner
After running the script we will need enter username and password in the window
And we will get following result
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