Hi @Shuvajit Roy,
According to this article, SharePoint mobile app works best for users working on intranet sites while joined to a corporate network if your SharePoint environment is on-premises. And the SharePoint app for Windows 10 Mobile will not connect to an on-premises SharePoint Server farm at this time.
Besides, SharePoint mobile app only supports Windows authentication (NTLM) and Forms Based Authentication. It does not support: ADFS, Kerberos, Basic Authentication, Digest Authentication, self-signed SSL or Multiple Authentication types in one zone. Check whether your authentication method meets the requirements.
Hope my answer helps. Just comment here if you still have any other questions.
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