Thanks for posting this question.
As I understand from the issue description, you are getting null values for the custom metadata fields that you wanted to transition to the Search Index as retrievable fields. You also tried to include a pre-defined blob property metadata_storage_content_type in the Search Index, but the new field is always null.
While I'm checking on this, kindly check the logs to fetch more details about the error: Diagnostic settings.
Troubleshooting common indexer errors and warnings in Azure AI Search