@Admin Richard Thank you for posting your question in Microsoft Q&A, apologize for any inconvenience caused on this.
Based on the shared information, it looks like you are trying to pass Setting Value as $null which is not accepted instead can you try resetting the cipher suite value to this TLS_RSA_WITH_AES_128_CBC_SHA which is the least cipher suite as mentioned in this blog post.
Post changing the cipher suite to above suggested I would suggest you to retry the scaling up your app service plan.
Also, if you are facing the issues in changing/resetting the cipher suites of app service through PowerShell or through cmdlets. I would suggest you change the Cipher suite using the portal under the configuration --> General Settings as shown below.
Feel free to reach back to me if you have any questions on this.