An extremely vague question, but in short: to validate or something with data in a database, you need to have an understanding of the business the database is to serve. Not a complete knowledge, but you at least need to have an idea. And you need to have access to people who can fill in.
And, of course, you need to have an understanding what you are supposed to "validate". I suppose that someone has given you the task who can clarify.
I've been in the situation a few times where I have had reason to look into an unknown database. Not exactly for validation, but rather to extract data. One thing which is extremely helpful is when the tables and columns have meaningful names. If names are like KONWIZBT, you will need to ask for documentation. Existing FK constraints are also very helpful to understand how tables are connected.