Hi @Tim Dawson - Thanks for reaching out.
If we check based on region the archive tier is supported in the UK South Region
However checking based on redundancy, the archive tier isn’t supported for ZRS account and below are reference links:
https://learn.microsoft.com/en-us/azure/storage/blobs/access-tiers-overview
https://learn.microsoft.com/en-us/azure/storage/common/storage-redundancy
So that seem to be the issue in here. If you have changed the redundancy you might the limitation. You can test with any supported configuration as well.
Hope that helps!