There is an extra ( before sum, it should be:
Select cd.continent, cd.location, cd.date, cd.population, cv.new_vaccinations , SUM(CONVERT(bigint,cv.new_vaccinations)) OVER (partition by cd.location order by cd.location, cd.Date) as RollingPeopleVaccinated From CovidData..CovidDeaths cd Join CovidData..CovidVaccination CV On cd.location = cv.location and cd.date = cv.date Where cd.continent is not null Order by 2,3