Thank you for posting your query on Microsoft Q&A, from above description I could understand that you have applied session control app monitor policy for salesforce, but this is not working when Salesforce team is using chrome extension.
Please do correct me if this is not the case by responding in the comments section.
As per Pre-onboarded apps Salesforce for already onboarded with both access and session controls for Microsoft Entra ID. However only following browser versions are supported.:
We don't have a way to exlude any browser extension from the policy however, session controls are built to work with any browser on any major platform on any operating system, we support the following browsers:
- Microsoft Edge (latest)
- Google Chrome (latest)
- Mozilla Firefox (latest)
- Apple Safari (latest)
Kindly consider updating the browser to latest version and confirm the behavior, if this does not work then consider testing with Microsoft Edge and confirm the behavior.
Please "Accept the answer (Yes)" and "share your feedback ". This will help us and others in the community as well.
Thanks,
Akshay Kaushik