Hi, @DukenTee
Thank you for posting in Microsoft Q&A forum.
Yes, SCCM has the real-time function called CMPivot. We can use CMPivot Query to find local administrator accounts.
Use the below SCCM CMPivot query to find local administrator accounts.
Administrators | where Name !contains 'Administrator' and Name !contains 'Domain Admins'
For more information, please refer to Prajwal Desai's article:
Find Local Administrator Accounts with SCCM CMPivot Query
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