Hi @Paul Wright,
Thank you for posting in this community.
First, please install PnP module first:
Install the PnP PowerShell Module for SharePoint Online.
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You can use this PowerShell to get the policies used by site:
# Connect to your SharePoint Online site
Connect-PnPOnline -Url "https://yourtenant.sharepoint.com/sites/yoursite"
# Get the policies applied to the site collection
Get-PnPSitePolicy
Reference: Get-PnPSitePolicy.
Note: Microsoft is providing this information as a convenience to you. The sites are not controlled by Microsoft. Microsoft cannot make any representations regarding the quality, safety, or suitability of any software or information found there. Please make sure that you completely understand the risk before retrieving any suggestions from the above link.
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