Hi @David Frith
We checked your command result and the Autodiscover URL is no issue.
So please check if you make the corresponding change in your Teams organization to enabled shared SIP address space with your on-premises deployment.
To enable shared SIP address space in your organization, establish a remote PowerShell session with Teams, and then run the following cmdlet:
Set-CsTenantFederationConfiguration -SharedSipAddressSpace $true
Besides, we found that a user's coexistence mode impact's what functionality is available in the user's Teams client. This means that the value of mode can take precedence over the value of other policy settings, depending on the mode. For more details, you could refer to:
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