Closing comment -
There is a glich in Window app service plan which make app service plan spike in 24 hrs at regular interval but its come for short life time. So, you will not be able to dianose which app service is creating this issue.
when you raise case with tech, they will also not able to find the issue and they just recommend to move monitor the avg aggregation instead of max aggregation,
Microsoft product team shoud look into this and must resolve it.
Thanks