Hello
To achieve your desired settings in Windows 11, follow these steps:
Password Prompt at Startup:
Press Windows + R to open the Run dialog box.
Type netplwiz and press Enter.
In the User Accounts window, select your user account.
Check the box that says “Users must enter a user name and password to use this computer.”
Click Apply and enter your current password if prompted.
Password Prompt after Hibernation:
Open Settings (Windows + I).
Go to Accounts > Sign-in options.
Under Require sign-in, select When PC wakes up from sleep and set it to Every time.
Disable Password Prompt after Sleep:
Open Settings (Windows + I).
Go to Accounts > Sign-in options.
Under Require sign-in, set it to Never for sleep mode.
These steps should help you configure your system to ask for a password only at startup and after hibernation, but not after sleep.