Thank you for posting this in Microsoft Q&A.
Yes, All Microsoft Entra Connect Sync 1.x versions are unsupported, and synchronization does not function. Versions of Microsoft Entra Connect Sync 2.x retire 12 months from the date that a newer version is released.
Continuous enhancements are made to Microsoft Entra Connect, including security fixes, bug resolutions, and improvements in serviceability, performance, and scalability. Ensuring your servers are updated with the latest releases of Microsoft Entra Connect is crucial. So, I suggested instead of upgrading to the latest version of Microsoft Entra Connect, use cloud sync. Azure AD Cloud Sync is the next generation of sync tools to provision users and groups from AD into Azure AD. It features a lightweight agent and is fully managed from the cloud, and it upgrades to newer versions automatically, so you never have to worry about upgrading again.
Regarding your goal of moving to a Hybrid join, it's important to note that Entra Connect would be required for this. Entra Connect provides a smoother SSO experience for users who need to access network shares on AD-joined servers. In this situation, I would recommend opting for Entra Connect.
To add an agent to another server or move the sync agent to a new server
You should upgrade the existing current EntraConnect version to the latest for your server version.
For your reference: Microsoft Entra Connect: Version release history
A similar inquiry on the Microsoft Q&A platform may be useful for migrating Azure AD Connect to a new server: https://learn.microsoft.com/en-us/answers/questions/1287797/how-to-migrate-azure-ad-connect-to-a-new-server
Hope this helps. Do let us know if you any further queries.
Thanks,
Navya.