hi I made changes in my question for better understanding. Thank you for making this program more complete.
Add Form Name 'VirtualMachine' with txt File Designer.vb.txt 
Public Class VirtualMachine
#Region "Initialization for data outside the program"
Dim dtUsers As New DataTable
Dim dtSetting As New DataTable
Private Sub VirtualMachine_Load(sender As Object, e As EventArgs) Handles MyBase.Load
dtSetting.Columns.Add("ID", GetType(Integer))
dtSetting.Columns.Add("SettingName")
dtSetting.Columns.Add("SettingValue")
dtSetting.Rows.Add({0, "Users", "Admin,Admin"})
dtSetting.Rows.Add({1, "RememberMe", ""})
dtUsers.Columns.Add("ID", GetType(Integer))
dtUsers.Columns.Add("UserName")
dtUsers.Columns.Add("UserPassword")
dtUsers.Columns.Add("UserType")
dtUsers.Columns.Add("Hit")
dtUsers.Rows.Add({0, "Admin", "Admin", "Admin", "Admin"}) 'is Default User
dgvUsers.DataSource = dtUsers
dgvSetting.DataSource = dtSetting
End Sub
Private Sub butExecute_Click(sender As Object, e As EventArgs) Handles butExecute.Click
LoadApp()
End Sub
#End Region
#Region "Bringing data from outside and initial settings"
Dim dtGetUsers As New DataTable
Dim dtGetSetting As New DataTable
Dim DicCheckUsers As Dictionary(Of String, String)
Sub LoadApp()
dtGetUsers = dtUsers.Copy ' Get Data from outside
dtGetSetting = dtSetting.Copy ' Get Data from outside
txtPassword.Text = ""
SyngUsers()
butViewSettingIfIsAdmin.Enabled = False
lblCurrentUser.Text = ""
comUserName.Items.Clear()
Dim GetCompute As Object = dtGetSetting.Compute("Min(SettingValue)", "[SettingName]='RememberMe'")
If GetCompute.ToString = "" Then
GetCompute = dtGetSetting.Compute("Min(SettingValue)", "[SettingName]='Users'")
DicCheckUsers = Dict_StringToDic_OfStrStr(GetCompute)
comUserName.Items.AddRange(DicCheckUsers.Keys.ToArray)
grpLoginForm.Visible = True
Else
End If
End Sub
Function Dict_StringToDic_OfStrStr(inString As String, Optional separator1 As String = "|", Optional separator2 As String = ",") As Dictionary(Of String, String)
Dim MyString As String = inString ' "Admin,Admin|Mansour,1394"
' Dim separators() As Char = '{"|"c}
Dim Result = MyString.Split(separator1).
Select(Function(x) x.Split(separator2)).
ToDictionary(Function(x) x(0), Function(x) x(1))
Return Result
End Function
#End Region
Private Sub butLoginOk_Click(sender As Object, e As EventArgs) Handles butLoginOk.Click
Dim row As DataRow()
Dim GetCompute As Object
If txtPassword.Text = DicCheckUsers(comUserName.Text) Then
If chkRememberMe.Checked Then
row = dtSetting.Select("[SettingName]='RememberMe'")
row(0).Item("SettingValue") = txtPassword.Text
End If
row = dtUsers.Select("[UserName]='" & comUserName.Text & "'")
GetCompute = dtUsers.Compute("Min(UserType)", "[UserName]='" & comUserName.Text & "'")
grpSettingOnlyAdminType.Visible = False
grpLoginForm.Visible = False
lblCurrentUser.Text = comUserName.Text
If GetCompute.ToString = "Admin" Then
InitialSetupOfAdmins()
End If
grpMainForm.Visible = True
Else
End If
End Sub
Sub InitialSetupOfAdmins()
butViewSettingIfIsAdmin.Enabled = True
lstUser.Items.Clear()
For Each row As DataRow In dtUsers.Rows
lstUser.Items.Add(Join(row.ItemArray, ","))
Next
End Sub
Private Sub butViewSettingIfIsAdmin_Click(sender As Object, e As EventArgs) Handles butViewSettingIfIsAdmin.Click
grpSettingOnlyAdminType.Visible = Not grpSettingOnlyAdminType.Visible
End Sub
Private Sub butExit_Click(sender As Object, e As EventArgs) Handles butExit.Click
grpLoginForm.Visible = False
grpMainForm.Visible = False
End Sub
Private Sub butAddUser_Click(sender As Object, e As EventArgs) Handles butAddUser.Click
Dim MaxId As Integer = dtUsers.Compute("Max([ID])", "") + 1
Dim Prompt As String = "Please enter the data in this order." & vbNewLine & "ID,User Name,Password,Type,Hit" & vbNewLine & "Sample:1,Jiachen Li,1234,User,Rev4321"
Dim sttGetRow As String = InputBox(Prompt, DefaultResponse:=MaxId & ",Jiachen Li,1234,User,Rev4321")
lstUser.Items.Add(sttGetRow)
dtUsers.Rows.Add(Split(sttGetRow, ","))
SyngUsers()
End Sub
Private Sub butEditUser_Click(sender As Object, e As EventArgs) Handles butEditUser.Click
If lstUser.SelectedIndex > -1 Then
lstUser.SelectedItem = InputBox("Edit", DefaultResponse:=lstUser.SelectedItem)
End If
End Sub
Private Sub butSingOut_Click(sender As Object, e As EventArgs) Handles butSingOut.Click
End Sub
Sub SyngUsers()
Dim GetAllUserPasword As String = ""
For Each row As DataRow In dtUsers.Rows
GetAllUserPasword += IIf(GetAllUserPasword <> "", "|", "") & row.Item("UserName") & "," & row.Item("UserPassword")
Next
Dim rows As DataRow() = dtSetting.Select("[SettingName]='Users'")
rows(0).Item("SettingValue") = GetAllUserPasword
End Sub
End Class