Hi @Christian Carrasco , this is caused by the fact that your user accounts are synced from your on-premises Active Directory to Entra ID using Entra Connect. When you use the "Run as different user" feature, it is trying to authenticate the user using their Entra ID account, which is based on their email address.
To work around this issue, you can use the following format when entering the username in the "Run as different user" dialog box:
<domain>\<username>
For example, if your on-premises domain is "contoso.com" and your username is "jdoe", then you would enter the following in the "Run as different user" dialog box:
contoso\jdoe
Please let me know if you have any questions and I can help you further.
If this answer helps you please mark "Accept Answer" so other users can reference it.
Thank you,
James