Hello czql5v,
Thank you for posting in Microsoft Community forum.
Q1: how do I apply the new GPO to take precedence over the current GPO applied to that OU.
A1: You can try to adjust the order of the linked GPOs to ensure that the higher priority GPOs are processed last. Select a GPO and click the up or down arrows to move it. The GPOs are processed by the client device from the highest link order number to the lowest.
Link the GPO to the Domain - Windows Security | Microsoft Learn
Q2: Also is there a way of testing this using the GPO Policy Modeling?
A2: You can export gpresult to check the GPO apply result.
For checking Computer Configuration within gpresult, we can follow steps below.
Logon this machine using administrator account.
Open CMD (run as Administrator).
Type gpresult /h C:\gpo.html and click Enter.
Open gpo.html and check gpo setting under "Computer Details".
I hope the information above is helpful.
If you have any question or concern, please feel free to let us know.
Best Regards,
Daisy Zhou