Hello,
Based on my understanding of your problem, I recommend that you enable checking NPS auditing first, because after enabling NPS auditing, the event log will record any authentication failure errors. If NPS auditing is not enabled, you can open CMD as an administrator and run the following command.
auditpol /set /subcategory:"Network Policy Server" /success:enable /failure:enable
Then perform corresponding troubleshooting based on the error message. For details, you can refer to the following link:
Guidance for troubleshooting Network Policy Server - Windows Server | Microsoft Learn
Best regards
Zunhui