Hello Robby_McCarrell,
Thank you for posting in Microsoft Community forum.
To remove a CA, you can refer to steps in the link below.
Decommission a Windows enterprise CA - Windows Server | Microsoft Learn
To create a new one clean PKI, you can refer to steps in the link below.
For PKI Tier, you can read the link below.
Securing PKI: Planning a CA Hierarchy | Microsoft Learn
I hope the information above is helpful.
If you have any question or concern, please feel free to let us know.
Best Regards,
Daisy Zhou