Hello SenhorDolas,
Thank you for posting in Q&A forum.
Based on the description, as I understand, you have one-tier PKI, do you mean you cannot back up CA when you run Certification Authority Backup Wizard?
If so, you can try to check whether you can export CA root certificate with its private key(below).
Open Certilm.msc and find the root CA certificate, right click this root CA certificate and select All Tasks\Export.
Here is a similar thread with the shared steps, you can try if it is helpful to you.
migration csp to ksp
https://learn.microsoft.com/en-us/answers/questions/305322/migration-csp-to-ksp
References
Step-By-Step: Migrating The Active Directory Certificate Service From Windows Server 2008 R2 to 2019
How to move a certification authority to another server
I hope the information above is helpful.
If you have any questions or concerns, please feel free to let us know.
Best Regards,
Daisy Zhou
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