Hi, anonymous usertanBali-2856 ,
Does this issue occur on other users?
For the part
I created a development environment with a fresh SharePoint Server 2016 (with the latest patch) installation with Windows Server 2016 (with the latest patch). I was able to reproduce the issue.
Are you using the same client (the windows 10 machine) to save the word document? I am not sue if you are using the same account.
Please have a test to directly upload the file to drop off library outside word. If it works, it could be due to credential cache. Have test to remove the cache in credential manager and the temp files in your machine.
Any new information will be helpful.
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