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@Greg@CoV ,
If you enabled Send all intranet sites to Internet Explorer policy then all intranet sites will get a load in IE mode in the Edge browser without configuring the Enterprise mode site list.
IE mode can be configured as for all sites in the Local Intranet zone. You can remove individual sites from IE mode using an Enterprise Mode Site List.
If you don't want to load all the intranet sites in the IE mode or want to set specific document mode or enterprise mode, other settings for any specific site then you need to configure the Enterprise mode site list.
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