Hi,
I know little about IIS SMTP relay so my suggestion might not help.
We can compare values of new and old allowed IPs set in step5 and step6 of How to: Setup A SMTP Relay In Windows 2012 R2 – IIS 6. Or we can increase values set in step6. Maybe the limit is not big enough to log new allowed IPs.
I don't understand what's the meaning of step8 but please
set all the devices that need SMTP relay to point to the new SMTP server you just setup and test
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