The server will only use 1 NIC to transfer out any file. As you are trying to copy file from 10.201.9.201, so it will be the second NIC to pick the job.
You will have to do some extra configuration in order to let 2 or more NIC to do the file transfer out. Please read this blog for more detail.
using-the-multiple-nics-of-your-file-server-running-windows-server-2008-and-2008-r2