Thanks for letting me know.
Since you’re working with additional storage then it is not OSV drive type you should check, could you confirm whether it's an internal secondary SSD or HDD (Fixed Disk Volume – FDV), or an external USB drive (Removable Disk Volume – RDV)?
You can check the drive type directly on the BitLocker page. The Key ID on the recovery screen should match the specific drive you're trying to unlock.
If it’s a secondary internal drive, look for FDV (Fixed Disk Volume). If it’s an external USB drive, it should show as RDV (Removable Disk Volume).
Once we know the drive type, we can make sure you're using the correct recovery key for that device. Let me know what you find.