@Chetar Ruby
Hi,
From your description, it seems you tried to boot your 21H1 image including (install.wim) which has been modified and captured by DISM. However it didn't work, as you suppose that 21HI.ISO might only support install.esd from Sources folder. Hereby I suggest you try the following operations to convert file format.
You could Convert ESD file to WIM using DISM in Windows 10
https://www.tenforums.com/tutorials/95308-convert-esd-file-wim-using-dism-windows-10-a.html?__cf_chl_jschl_tk__=22403c31866ef49eacc8c8df353427d237348407-1594014497-0-AfAVFmu664zt70i9FHsGs-h5vmLfENuIPSkILPeunDoEDxojsW7vEW0WU6wcSc4c0K5IpLN3Z8xhLZ-6-eciyClTALZK0IawFvrRrMDXdVGyq0EVoKroXL1XdIf32hWGN7a-XBjArT7b-gUfcEzVvsEEoDOCnFkeyNPDWrdDMgpWTQdknbjDHGjzqs1gkhIBXo1Vfs8MQBliaCLi4M53TgYivI1NKp04fRWM6qJcCniaRl75I7-7zZVbN761BkWN2uDoTbuUW-MQcS-xwloaHXLaRgU2jCopW8WNAiLoiI3y-0w2hH4IVEnfRLU5CC-6-0arbPrzLHlJnVD9yQ08ygkM7TsFvzDSw4jQS9TgdBnT
Please note: Information posted in the given link is hosted by a third party. Microsoft does not guarantee the accuracy and effectiveness of information.
Hope above information can help you.
============================================
If the Answer is helpful, please click "Accept Answer" and upvote it.
Note: Please follow the steps in our documentation to enable e-mail notifications if you want to receive the related email notification for this thread