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Hi Andrew, I am Paulo and I'd like to help.
Yes, it does and it is a one-way procedure. There's no turning back once it is off.
You might want to check this article as well
Does deactivating S mode affect every user?
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Anonymous
I have multiple users on my laptop with windows 11 S mode active. If I deactivate s mode on one user will it deactivate for the other users?
Windows for home | Windows 11 | Install and upgrade
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Anonymous
2022-11-12T07:45:28+00:00 Yes it will