Additional features, settings, or issues not covered by specific Microsoft Teams categories
Dear Max,
In my own experience with synced users, if those users you assign it an "Exchange Online" service and Teams license, they can use Teams and communicate with external/guest users without any problem, first you should to verify overall configuration for "external/guest" sharing and communications:
https://docs.microsoft.com/en-us/microsoft-365/...
See more in below link:
https://docs.microsoft.com/en-us/microsoftteams...
Then verify external communication in Skype for business legacy portal:
https://docs.microsoft.com/en-us/SkypeForBusine...
Now, you should wait up to 48 hours. Any time you change the external communications settings, it can take up to 24 hours for the changes to populate across all the data centers.
After, open Microsoft Teams, create a new team, and add guest as a members, see the process in below link:
https://support.microsoft.com/en-us/office/add-...
What guests has to do:
https://docs.microsoft.com/en-us/MicrosoftTeams...
By other hand, if your users doesn't has an "Exchange Online" license, instead has a On-prem Exchange server, the process will be different, and a little more complex.
Regards,
Renzo.