In order for the Graph to be able to access on-premises data, you need to configure integration as detailed here: https://learn.microsoft.com/en-us/graph/hybrid-rest-support#requirements-for-the-rest-api-to-work-in-hybrid-deployments
Graph API Calendar return 404 not found
Harry Huang (Crystal Group)
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This is Exchange on-premises server mailbox account, and it does not have an Exchange Online mailbox. I suppose the API can work in hybrid deployments?
*If I use another O365 account to login and try to get this mailbox schedule via "/calendar/getSchedule", it works.