Using older versions of Outlook for Mac for personal email and calendar
Dear Ali,
Good day! Thank you for posting to Microsoft Community. We are happy to help you.
According to your description, it seems when you deliver an email to recipient and you got the Non delivery report. Regarding this point, we kindly suggest you refer I can't send or receive messages with Outlook for Mac (microsoft.com) to get more details about why you are not available to send out emails in Outlook for Mac.
After check it, if every setting had set up properly as our official article provided but issue still persists, then we kindly suggest you refer Contact support within Outlook for Mac (microsoft.com) to contact our dedicated Outlook for Mac support team, for Outlook for Mac issues, experts there have abundant experience deal with it, they might available to provide further assists to help you to deliver your emails as normal.
Sincerely,
Tommy | Microsoft Community Moderator