Using New Outlook on Windows for professional communication and productivity
Dear William6379
Thank you for posting in the Microsoft Community.
I understand your situation and needs. First of all, this postmaster email is not a spam or phishing email. It is an official Microsoft Unable to Send Mail error report. You can refer this link to know about it.
Outlook has a send size limit of 25MB. you can check if you are sending an email that exceeds the size limit and cannot be sent. You can refer to this link for outlook sending restrictions.
Sending limits in Outlook.com - Microsoft Support
I hope that my reply will be helpful to you.
Please feel free to let me know if you have any further updates, thank you.
Best Regards,
Simon.W - MSFT | Microsoft Community Support Specialist