The TabControl that comes with Winform does not support this setting.
You can customize a TabControl and redraw this control.
Rounded corners for a Tab Control (WinForms)
Or you can create a WPF user control and use it in your project.
<Grid>
<TabControl Margin="10" BorderBrush="Gainsboro">
<TabControl.Resources>
<Style TargetType="TabItem">
<Setter Property="Template">
<Setter.Value>
<ControlTemplate TargetType="TabItem">
<!--The four values of CornerRadius represent the four corners of the TabItem.-->
<Border Name="Border" BorderThickness="1,1,1,0" BorderBrush="Gainsboro" CornerRadius="8,8,0,0" Margin="2,0">
<ContentPresenter x:Name="ContentSite"
VerticalAlignment="Center"
HorizontalAlignment="Center"
ContentSource="Header"
Margin="10,2"/>
</Border>
<ControlTemplate.Triggers>
<Trigger Property="IsSelected" Value="True">
<Setter TargetName="Border" Property="Background" Value="LightSkyBlue" />
</Trigger>
<Trigger Property="IsSelected" Value="False">
<Setter TargetName="Border" Property="Background" Value="GhostWhite" />
</Trigger>
</ControlTemplate.Triggers>
</ControlTemplate>
</Setter.Value>
</Setter>
</Style>
</TabControl.Resources>
<TabItem Header="General">
<Label Content="Content goes here..." />
</TabItem>
<TabItem Header="Security" />
<TabItem Header="Details" />
</TabControl>
</Grid>
This is a simple example. If you have more requirements for this control, you can post a new question with the windows-wpf tag.
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