A family of Microsoft word processing software products for creating web, email, and print documents.
It is a problem with file association for .doc and .docx registry enteries.
Click on Start > Default programs > Select Associate a file type or protocol...
Check for .doc and .docx file association if it opens using Microsoft Word.
If that does not resolve the problem you can open registry.
Run > regedit > Take a backup.
Navigate to Hkey Classes Root > .doc and .docx.
Delete them but you might need to ask a friend to send you the registry enteries for this file extentions.
You can simply double click on the registry enteries that you get from your friend to merge them.
Lastly you can open C:<Root Directory> Program Files (64bit open program files x86) >
Microsoft Office > Office 14 > Check compatibility for Winword.exe. You may also delete it and add it once again.