A family of Microsoft word processing software products for creating web, email, and print documents.
Temporary files created while using Office programs is different than the shadow copies created on windows.
You may refer the article to know why Word creates temporary files:
http://support.microsoft.com/kb/211632
Copies of files and folders that Windows automatically saves as part of a restore point can be retrieved from the shadow copies created on the computer or network.
If System Protection is turned on, Windows automatically creates shadow copies of files that have been modified since the last restore point was made.
To know about why shadow copies are created, you may refer the below link: