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Aha! This makes more sense now.
Since the button code is on frmMatterScheduleSelection, the Me. refers to that form, not to the form you're trying to open.
Try changing the code to
Private Sub cmdMatterSchedule_Click()
On Error GoTo Err
DoCmd.OpenForm "frmMatterSchedule", _
WhereCondition:="[DateSent] IS NULL"
DoCmd.GoToControl ("Hdr")
Exit_Err:
Exit Sub
Err:
MsgBox Err.Description, , "Sorry"
Resume Exit_Err
End Sub
and omit the Filter code altogether.
You may also need to move the GoToControl line to the Load event of frmMatterSchedule.