A family of Microsoft relational database management systems designed for ease of use.
As Tom said, you really can't do that. What you've found is information on how to "wrap" a .NET DLL that YOU have created, and allow it to be used in VBA. You could conceivably create a DLL that includes all the calls to the smtp class, but you'll still find troubles with that (.NET permissions and such may prevent you from doing this).
There are other ways to send emails in Access, like CDO and vbSendMail. Those don't require anything other than an SMTP server, and you can generally do everything you need with them.
If you're only dealing with Outlook, I've found vbMAPI from www.everythingaccess.com to be the best tool to use.