Microsoft 365 features that help users manage their subscriptions, account settings, and billing information.
No, dirsync is one-way process. Only very few attributes are synced back to on-prem. Best thing to do is to export the Azure AD users and their attributes via PowerShell or the Graph API, then use the exported data to create the accounts in the new AD.
Once you have recreated the users, you can use the so-called soft-match process to "link" them to the O365 accounts: support.microsoft.com/.../2641663