It is possible to use an unbound multi-select list box, provided that there are no non-key attributes of the relationship type to be entered. It does require code in the form's module to read data from the table which models the relationship type
and select the relevant items in the list box, and conversely, to loop through the list box's ItemsSelected collection and insert into or delete rows from the table, the latter when an item in the list box is deselected.
You'll find an example of such a list box in StudentCourses.zip in my public databases folder at:
https://onedrive.live.com/?cid=44CC60D7FEA42912&id=44CC60D7FEA42912!169
Note that if you are using an earlier version of Access you might find that the colour of some form objects such as buttons shows incorrectly and you will need to amend the form design accordingly.
If you have difficulty opening the link copy its text (NB, not the link location) and paste it into your browser's address bar.
However, note that it is not possible to assign a value to the Status attribute of the relationship type in this way, as is done in the conventional interface of a form/subform. Even if there are no non-key attributes of the relationship type, unless there
are very cogent reasons for using a list box I would recommend the use of the conventional form/subform interface, which is code free and very easy to implement.