Hi Emily, I'm an independent adviser and will try to help. In the Relationships Window you can click on the line between the table to select the relationship. You can then right click on the line and select Edit Join and edit the relationship there. But if relationship was set as 1:1; its likely that both field are set for No Duplicates in both tables. If P_Manager is a field in your Orders table set for Duplicates OK. Then a relationship between other tables shouldn't matter.
So another place to look is in the indexes for the Orders table. You may have a composite index that is causing the problem.
If you need further clarification in this feel free to ask.