Hi Finnbee,
Thanks for the updates. Power apps form may take a few mins to take effect, so I would suggest you wait for a while. Additionally, please make sure you select Power Apps form as form for your list, you may go to List settings>Form settings to change this:
Additionally, please note the Form create from Power Apps may not work for the details panel, it works when you select New+ to create a new item, select a item and click “Edit”, and open detail panel and select “Edit all”. May I know does the power apps work if you select New+ or select “Edit”? Here is an example of test results on my side.
If the form works, you may turn off “Allow items in this list to be edited using Quick Edit and the Details Pane?” from List Setting > Advance Settings to reduce confusion when user try to edit an existing item.
Best Regards,
Clark